catena-Poly[1,2,2-trimethylcyclopentane-1,3-diammonium [aluminate(III)-μ-(hydrogen phosphato)-μ-phosphato]]
نویسنده
چکیده
In the title compound, {(C(8)H(20)N(2))[Al(HPO(4))(PO(4))]}(n), the Al(III) atom is coordinated by four O atoms from two HPO(4) (2-) and two PO(4) (3-) groups in a distorted tetra-hedral geometry. Each AlO(4) unit shares four O atoms with four adjacent PO(4) units, leading to an anionic chain along [100]. The negative charge of the chain is compensated by doubly protonated camphoric amine cations. N-H⋯O hydrogen bonds connect the cations and the anionic chains. O-H⋯O hydrogen bonds are present in the chain.
منابع مشابه
Poly[octaaquadi-μ-phosphato-trinickel(II)]. Corrigendum
A correction is made to the name of the first author in Shouwen, Wang, Gao, Wen & Zhou [Acta Cryst. (2008), E64, m259].[This corrects the article DOI: 10.1107/S1600536807067050.].
متن کاملcatena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydroxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]
The asymmetric unit of the polymeric title compound, [Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5)](n), consists of two Na(I) ions, one 2'-hydr-oxy-1,1'-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octa-hedral coordination geometry. The phosphate anion coordinates to one Na(I) ion and the ethanol mol-ecule coordina...
متن کاملPoly[octaaquadi-μ-phosphato-trinickel(II)]
In the title compound, [Ni(3)(PO(4))(2)(H(2)O)(8)](n), which was synthesized hydro-thermally, all the Ni atoms are located in slightly distorted octa-hedral coordination environments. Two phosphate groups and two Ni atoms share a centrosymmetric four-membered ring and an eight-membered ring such that the four-membered ring is inside the eight-membered ring. The eight-membered rings are connecte...
متن کاملPoly[[μ-bis(4-nitrophenyl) phosphato-κ2 O,O′]sodium]
The title compound, [Na(C12H8N2O8P)], consists of one Na(+) cation and one bis-(p-nitro-phen-yl)phosphate anion with a considerable distortion of the phosphate tetra-hedron due to the presence of two P-O ester bonds. The anion bridges five Na(+) cations whereby each cation is chelated by the nitro O atoms of one anion and bonded via a nitro O atom and phosphate O atoms to four other anions. Thi...
متن کاملcatena-Poly[bis(1,3-benzothiazol-3-ium) [[dichloridoantimonate(III)]-di-μ-chlorido-μ-oxido-[chloridoantimonate(III)]-μ-chlorido]]
The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012